The author of 《Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]-: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides》 were Liu, He; Shen, Qilong. And the article was published in Organic Chemistry Frontiers in 2019. Electric Literature of C8H8BrNO2 The author mentioned the following in the article:
The synthesis and characterization of a bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]- and its reactions with a variety of activated heteroaryl bromides, chlorides and iodides were described. These results showed that complex [Ph4P]+[Cu(CF3)2]- can serve as a trifluoromethylating reagent. In the experiment, the researchers used many compounds, for example, Ethyl 3-bromopicolinate(cas: 434319-41-2Electric Literature of C8H8BrNO2)
Ethyl 3-bromopicolinate(cas: 434319-41-2) belongs to pyridine. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. As ligands, solvents, and catalysts they facilitate reactions; thus descriptions of these new ligands and their applications abound each year.Electric Literature of C8H8BrNO2