Vantomme, Ghislaine’s team published research in Journal of the American Chemical Society in 136 | CAS: 2215-33-0

Journal of the American Chemical Society published new progress about 2215-33-0. 2215-33-0 belongs to pyridine-derivatives, auxiliary class Pyridine,Amine, name is 2-((2-(Pyridin-2-yl)hydrazono)methyl)pyridine, and the molecular formula is C15H21BO3, Formula: C11H10N4.

Vantomme, Ghislaine published the artcileAdaptation in Constitutional Dynamic Libraries and Networks, Switching between Orthogonal Metalloselection and Photoselection Processes, Formula: C11H10N4, the publication is Journal of the American Chemical Society (2014), 136(26), 9509-9518, database is CAplus and MEDLINE.

Constitutional dynamic libraries of hydrazones aAbB and acylhydrazones aAcC undergo reorganization and adaptation in response to a chem. effector (metal cations) or a phys. stimulus (light). The set of hydrazones [1A1B, 1A2B, 2A1B, 2A2B] undergoes metalloselection on addition of zinc cations which drive the amplification of Zn(1A2B)2 by selection of the fittest component 1A2B. The set of acylhydrazones [E-1A1C, 1A2C, 2A1C, 2A2C] undergoes photoselection by irradiation of the system, which causes photoisomerization of E-1A1C into Z-1A1C with amplification of the latter. The set of acyl hydrazones [E-1A1C, 1A3C, 2A1C, 2A3C] undergoes a dual adaptation via component exchange and selection in response to two orthogonal external agents: a chem. effector, metal cations, and a phys. stimulus, light irradiation Metalloselection takes place on addition of zinc cations which drive the amplification of Zn(1A3C)2 by selection of the fittest constituent 1A3C. Photoselection is obtained on irradiation of the acylhydrazones that leads to photoisomerization from E-1A1C to Z-1A1C configuration with amplification of the latter. These changes may be represented by square constitutional dynamic networks that display up-regulation of the pairs of agonists (1A2B, 2A1B), (Z-1A1C, 2A2C), (1A3C, 2A1C), (Z-1A1C, 2A3C) and the simultaneous down-regulation of the pairs of antagonists (1A1B, 2A2B), (1A2C, 2A1C), (E-1A1C,2A3C), (1A3C, 2A1C). The orthogonal dual adaptation undergone by the set of acylhydrazones amounts to a network switching process.

Journal of the American Chemical Society published new progress about 2215-33-0. 2215-33-0 belongs to pyridine-derivatives, auxiliary class Pyridine,Amine, name is 2-((2-(Pyridin-2-yl)hydrazono)methyl)pyridine, and the molecular formula is C15H21BO3, Formula: C11H10N4.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem