Smoll, Karena A.’s team published research in Organometallics in 36 | CAS: 338800-13-8

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C7H7ClN2S, Application In Synthesis of 338800-13-8.

Smoll, Karena A. published the artcilePhotolysis of Pincer-Ligated PdII-Me Complexes in the Presence of Molecular Oxygen, Application In Synthesis of 338800-13-8, the publication is Organometallics (2017), 36(7), 1213-1216, database is CAplus.

The reactions of t-BuPNP and t-BuPCP PdII-Me complexes (t-BuPNP = 2,6-bis[(di-tert-butylphosphino)methyl]pyridine and t-BuPCP = 2,6-bis[(di-tert-butylphosphino)methyl]phenyl) with O2 are described and compared with the reported O2 reactivity of related PdII-Me complexes. [(t-BuPNP)PdMe]Cl was found to react with O2 upon photolysis resulting in oxidation of the pincer ligand backbone to produce a (t-BuPNO)PdCl complex. In contrast, photolysis of (t-BuPCP)PdMe with O2 resulted in oxidation of the Pd-Me group to form (t-BuPCP)PdOCO2H. Isotopic labeling, radical initiators, and solvent studies were used to gain insight into the mechanisms of these unusual reactions of late metal alkyls with mol. oxygen.

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C7H7ClN2S, Application In Synthesis of 338800-13-8.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem