Wang, Qingqing published the artcilePreparation of 2-pyridylboronic acid, Computed Properties of 197958-29-5, the publication is Bengbu Yixueyuan Xuebao (2010), 35(10), 1043-1045, database is CAplus.
The means of preparing 2-pyridylboronic acid was investigated. The product was synthesized with 2-bromopyridine, tris-trimethylsilylborate and iPrMgCl as Grignard reagents under N2, and identified by 1H-NMR. 2-Pyridylboronic acid was synthesized with the yield of 67.7% on conditions of n(tris-trimethylsilylborate): n(2-bromopyridine)=2:1; the reaction temperature was 0 degree, the reaction time 3 h and the hydrolysis temperature 0 degree. 2-Pyridylboronic acid can be synthesized by Grignard reaction on moderate conditions with high yield, which may contribute to the study of pyridine drugs.
Bengbu Yixueyuan Xuebao published new progress about 197958-29-5. 197958-29-5 belongs to pyridine-derivatives, auxiliary class Pyridine,Boronic acid and ester, name is 2-Pyridinylboronic acid, and the molecular formula is C19H14Cl2, Computed Properties of 197958-29-5.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem