Martin, Jaime et al. published their research in Angewandte Chemie, International Edition in 2022 | CAS: 4373-61-9

2-(m-Tolyl)pyridine (cas: 4373-61-9) belongs to pyridine derivatives. Pyridine has a dipole moment and a weaker resonant stabilization than benzene (resonance energy 117 kJ·mol−1 in pyridine vs. 150 kJ·mol−1 in benzene). Reduced pyridines, namely tetrahydropyridines, dihydropyridines and piperidines, are found in numerous natural and synthetic compounds. The synthesis and reactivity of these compounds have often been driven by the fact many of these compounds have interesting and unique pharmacological properties. Name: 2-(m-Tolyl)pyridine

Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation was written by Martin, Jaime;Gomez-Bengoa, Enrique;Genoux, Alexandre;Nevado, Cristina. And the article was included in Angewandte Chemie, International Edition in 2022.Name: 2-(m-Tolyl)pyridine This article mentions the following:

A catalytic method to synthesize a broad array of cyclometalated (C-N)gold(III) [(ArPy)AuCl2] (120; Ar = substituted Ph, thienyl; Py = substituted 2-pyridyl, isoquinolinyl, pyrazolinyl, thiazolinyl; ArPy = benzo[h]quinoline) complexes is reported here. An unprecedented Rh-to-AuIII transmetalation allows the facile transfer of (C-N) ligands between these two metals in a redox-neutral process. The reaction employs com. available precursors and proceeds under mild and environmentally benign conditions. Both exptl. and computational studies support a multistep transmetalation from rhodium to gold as the underlying mechanism for these transformations. This process involves first, a rate-determining transfer of the C ligand followed by the subsequent incorporation of the N donor to form the monocyclometalated (C-N)gold(III) species. In the experiment, the researchers used many compounds, for example, 2-(m-Tolyl)pyridine (cas: 4373-61-9Name: 2-(m-Tolyl)pyridine).

2-(m-Tolyl)pyridine (cas: 4373-61-9) belongs to pyridine derivatives. Pyridine has a dipole moment and a weaker resonant stabilization than benzene (resonance energy 117 kJ·mol−1 in pyridine vs. 150 kJ·mol−1 in benzene). Reduced pyridines, namely tetrahydropyridines, dihydropyridines and piperidines, are found in numerous natural and synthetic compounds. The synthesis and reactivity of these compounds have often been driven by the fact many of these compounds have interesting and unique pharmacological properties. Name: 2-(m-Tolyl)pyridine

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem