Pd(II)-catalyzed o-aroylation of directing arenes using terminal aryl alkenes and alkynes was written by Khatun, Nilufa;Banerjee, Arghya;Santra, Sourav K.;Behera, Ahalya;Patel, Bhisma K.. And the article was included in RSC Advances in 2014.Recommanded Product: 2-Phenoxypyridine This article mentions the following:
A substrate-directed Pd-catalyzed o-aroylation strategy was demonstrated using new aroyl surrogates viz. terminal aryl alkenes and alkynes in the presence of TBHP. By a subtle change in catalyst from Cu to Pd, a differential selectivity was observed While terminal aryl alkenes/alkynes in the presence of Cu/TBHP were reported to act as o-aryloxy (ArCOO-) sources, the use of Pd/TBHP installed an aroyl (ArCO-) group at the ortho position with respect to the directing arenes. In the experiment, the researchers used many compounds, for example, 2-Phenoxypyridine (cas: 4783-68-0Recommanded Product: 2-Phenoxypyridine).
2-Phenoxypyridine (cas: 4783-68-0) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Recommanded Product: 2-Phenoxypyridine