Aqueous Suzuki-Miyaura Reaction with 0.6 Equivalent of Base: Green and Efficient Access to Biaryls and Unsymmetrical Terphenyls was written by Li, Xinmin;Teng, Yong;Feng, Fangfang;Hu, Qinghong;Yuan, Zeli. And the article was included in ChemistrySelect in 2018.Related Products of 4373-61-9 This article mentions the following:
A green and efficient protocol for the synthesis of biaryls by a Pd(OAc)2-catalyzed ligand-free Suzuki-Miyaura reaction was described. The reaction proceeded smoothly in water and gives good yields in the presence of 0.6 equivalent of base. Addnl., using bromo-N-methyliminodiacetic acid (MIDA) boronates as building block, one-pot double Suzuki-Miyaura reaction was achieved by controlling the amount of base and various unsym. terphenyls were prepared in moderate to good yields. In the experiment, the researchers used many compounds, for example, 2-(m-Tolyl)pyridine (cas: 4373-61-9Related Products of 4373-61-9).
2-(m-Tolyl)pyridine (cas: 4373-61-9) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Related Products of 4373-61-9