Recently I am researching about OXYGEN REDUCTION; ONE-POT; ASYMMETRIC EPOXIDATION; MOLECULAR-OXYGEN; ALLYLIC ALCOHOLS; NANOPARTICLES; PERFORMANCE; COMPLEXES; OLEFINS; ACIDS, Saw an article supported by the Key Technology R&D Program of Shandong Province [2019GGX102075]; DICP QIBEBT [DICP & QIBEBT UN201704]; Dalian National Laboratory for Clean Energy (DNL) Cooperation Fund, CAS [DNL201904]; Open Projects of State Key Laboratory of Physical Chemistry of the Solid State Surface (Xiamen University) [201808]; Royal Society (UK)Royal Society of London [NAF R2180695]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Song, T; Ma, ZM; Ren, P; Yuan, YZ; Xiao, JL; Yang, Y. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Safety of Phenyl(pyridin-2-yl)methanone
We herein report the fabrication of a bifunctional iron nanocomposite catalyst, in which two catalytically active sites of Fe-N-x and Fe phosphate, as oxidation and Lewis acid sites, were simultaneously integrated into a hierarchical N,P-dual doped porous carbon. As a bifunctional catalyst, it exhibited high efficiency for direct oxidative cleavage of alkenes into ketones or their oxidation into 1,2-diketones with a broad substrate scope and high functional group tolerance using TBHP as the oxidant in water under mild reaction conditions. Furthermore, it could be easily recovered for successive recycling without appreciable loss of activity. Mechanistic studies disclose that the direct oxidation of alkenes proceeds via the formation of an epoxide as intermediate followed by either acid-catalyzed Meinwald rearrangement to give ketones with one carbon shorter or nucleophilic ring-opening to generate 1,2-diketones in a cascade manner. This study not only opens up a fancy pathway in the rational design of Fe-N-C catalysts but also offers a simple and efficient method for accessing industrially important ketones and 1,2-diketones from alkenes in a cost-effective and environmentally benign fashion.
Welcome to talk about 91-02-1, If you have any questions, you can contact Song, T; Ma, ZM; Ren, P; Yuan, YZ; Xiao, JL; Yang, Y or send Email.. Safety of Phenyl(pyridin-2-yl)methanone
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem