Category: 1214363-66-2

Duan, Yu-Hao; Zhu, Xiao-Zhao; Zhang, Qian; Yang, Yang published an article in Inorganic Chemistry Communications. The title of the article was 《Molecular enantiopure homometallic Zn14L24 cubic cages with luminescence properties》.Product Details of 1214363-66-2 The author mentioned the following in the article:

Chiral homometallic high-nuclearity cages are rare and of synthetic challenge. Herein, the authors report the syntheses and structures of a pair of enantiopure homometallic high-nuclearity [Zn14L24]28+ cages. The mol. cage has a cubic framework with pseudo-O symmetry and encloses a large void inside. The chirality of the framework is directed by the point chirality of the chiral amine applied, which is verified by the crystal structure and CD studies. The formation processes are probed by NMR and CD studies. The cage complexes also possess blue luminescence properties. They represent the first enantiopure homometallic cubic cages and rare examples of high-nuclearity enantiopure cages. In the experimental materials used by the author, we found [3,4′-Bipyridine]-6-carboxylic acid(cas: 1214363-66-2Product Details of 1214363-66-2)

[3,4′-Bipyridine]-6-carboxylic acid(cas: 1214363-66-2) belongs to pyridine derivatives. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals. Product Details of 1214363-66-2

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Severance, Rachel C.; Ellsworth, Joe; Smith, Mark D.; Kelley, Jennifer; Peterson, LeRoy Jr.; zur Loye, Hans-Conrad published their research in Journal of Chemical Crystallography on December 31 ,2010. The article was titled 《Synthesis and Crystal Structure of the Coordination Complex Cu(ppca’)2(H2O)2 (ppca’ = 3,4′-Bipyridine-6-Carboxylic Acid)》.Formula: C11H8N2O2 The article contains the following contents:

The coordination complex Cu(ppca’)2(H2O)2 (1) was synthesized hydrothermally using the ligand 3,4′-bipyridine-6-carboxylic acid (ppca’). Complex 1 consists of pseudo-octahedral copper(II) units hydrogen bonded into a three-dimensional network that crystallizes in the monoclinic P21/n space group. In complex 1, a 5.3429(4), b 29.343(2), c 6.7940(5) Å, and β 110.635(2)°. The experimental part of the paper was very detailed, including the reaction process of [3,4′-Bipyridine]-6-carboxylic acid(cas: 1214363-66-2Formula: C11H8N2O2)

[3,4′-Bipyridine]-6-carboxylic acid(cas: 1214363-66-2) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the π-bonding aromatic system using its unhybridized p orbital. Formula: C11H8N2O2 Pyridine has a conjugated system of six π electrons that are delocalized over the ring.

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem