Category: 91-02-1

Recently I am researching about TRISULFUR RADICAL-ANION; MOLECULAR-OXYGEN; CLEAVAGE; IRON; SULFUR; OLEFINS; HYDROXYLATION; CHEMISTRY; BONDS; ACID, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21971174, 21772137]; PAPD; Soochow University. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Ai, JJ; Liu, BB; Li, J; Wang, F; Huang, CM; Rao, WD; Wang, SY. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Recommanded Product: 91-02-1

An iron-sulfur complex formed by the simple mixture of FeCl3 with S-3(center dot-) generated in situ from K2S is developed and applied to selective aerobic oxidation of terminal alkenes. The reaction was carried out under an atmosphere of O-2 (balloon) and could proceed on a gram scale, expanding the application of S-3(center dot-) in organic synthesis. This study also encourages us to explore the application of an Fe-S catalyst in organic reactions.

About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Ai, JJ; Liu, BB; Li, J; Wang, F; Huang, CM; Rao, WD; Wang, SY or concate me.. Recommanded Product: 91-02-1

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Recently I am researching about HETEROPOLYTUNGSTATE DERIVATIVES; HETEROGENEOUS CATALYSTS; CYCLOHEXANE OXIDATION; W-183 NMR; METAL; KEGGIN; PERFORMANCE; FUNCTIONALIZATION; HYDROCARBONS; OXYGENATION, Saw an article supported by the Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21571050, 21573056, 21771053, 21771054]; 2019 Student Innovative Pilot Plan of Henan University [201910475079]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Ma, XY; Wang, P; Liu, ZH; Xin, CH; Wang, SY; Jia, JG; Ma, PT; Niu, JY; Wang, JP. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Name: Phenyl(pyridin-2-yl)methanone

POM-supported metal carbonyl derivatives (PMCDs) represent a family of tremendous potential catalysts owing to their peculiar physical and chemical properties. Yet low-valence transition metal-substituted Dawson-type PMCD catalysts are uncommon. Hence, we synthesized a tricobalt-substituted PMCDs by conventional aqueous solution method, [Na(H2O)(5)](NH4)(7)[P2W15O56Co3(H2O)(3)(OH)(3)Re(CO)(3)]center dot 13H(2)O (1), and characterized by single crystal X-ray diffraction crystallography, IR, and thermogravimetric analyses (TGA), etc. The obtained compound 1 was employed as a catalyst for the oxidation of diphenylmethane (DPM) to benzophenone, giving 96.8% yield in the presence of tert-butyl hydroperoxide (TBHP) and pyridine. The control experiments indicate that Co metal ion plays an important role in the catalytic reactions. As a side note, the electrospray ionization mass spectrometry (ESI-MS) and UV spectroscopy showed that 1 can retain its integrity in solution, and magnetic measurements indicated that 1 exhibited a weaker ferromagnetic interaction at low temperature.

About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Ma, XY; Wang, P; Liu, ZH; Xin, CH; Wang, SY; Jia, JG; Ma, PT; Niu, JY; Wang, JP or concate me.. Name: Phenyl(pyridin-2-yl)methanone

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Recently I am researching about NI-II COMPLEXES; MOLECULAR-STRUCTURE; HYDROLYSIS; MECHANISM; LIGANDS; ESTERS; DRUGS; COBALT(III); DERIVATIVES; KINETICS, Saw an article supported by the CSIR-IndiaCouncil of Scientific & Industrial Research (CSIR) – India [09/028(1023)/2018-EMR-I]; DST-INSPIREDepartment of Science & Technology (India) [DST/INSPIRE Fellowship/2018/IF180018, DST/INSPIRE/03/2017/001850]; DST-WBDepartment of Science & Technology (India) [327(sanc)/ST/P/ST/15G-8/2016]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Dasgupta, S; Karim, S; Banerjee, S; Saha, M; Saha, KD; Das, D. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Safety of Phenyl(pyridin-2-yl)methanone

Three asymmetric tridentate acyl hydrazone Schiff base ligands namely L1, L2 and L3 were prepared via condensation of 4-methoxybenzohydrazide with picolinaldehyde, 1-(pyridin-2-yl)ethanone and phenyl(pyridin-2-yl)methanone respectively. Three bio-relevant mononuclear zinc(ii) complexes [Zn(L1)Cl-2]2H(2)O (1), [Zn(L2)Cl-2] (2) and [Zn(L3)Cl-2] (3) were synthesized by treatment of zinc(ii) chloride with the corresponding Schiff base ligands and characterised by the usual physicochemical techniques. The solid state structures of complexes 1 and 3 were evaluated by single crystal X-ray analysis. All complexes were able to hydrolyse the P-O bond of the phosphate monoester in 90% (v/v) DMSO-water medium using 4-nitrophenylphosphate (4-NPP) as the model substrate and the trend in their activity is 1 approximate to 2 > 3. On considering the highly efficient hydrolysis properties, complexes 1-3 were tested as potential therapeutic agents for cancer using HCT116 (human colorectal carcinoma), HepG2 (human hepatocellular carcinoma) and A549 (human non-small lung carcinoma) cells. Complex 2 showed the highest IC50 values for anti-cancer activity towards all three cell lines among the three complexes and complex 3 showed the least activity as observed in the phosphatase activity study. The internucleosomal degradation of DNA during apoptosis can be detected by cell death detection ELISA. DNA fragmentation that leads to cell death was examined and when induced by complex 2 in HepG2 cells a significant level of DNA fragmentation was observed at regular intervals of time.

Safety of Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Dasgupta, S; Karim, S; Banerjee, S; Saha, M; Saha, KD; Das, D or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Authors Wang, AW; Zhou, WY; Sun, ZH; Zhang, Z; Zhang, ZH; He, MY; Chen, Q in ELSEVIER published article about LAYERED DOUBLE HYDROXIDES; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; AEROBIC OXIDATION; AROMATIC KETONES; MEDIATED OXIDATION; MN; NI; ACETOPHENONE; ETHYLBENZENE in [Wang, Anwei; Zhou, WeiYou; Sun, Zhonghua; Zhang, Zhong; Zhang, Zhihui; He, MingYang; Chen, Qun] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China in 2021, Cited 73. Product Details of 91-02-1. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1

Developing efficient heterogeneous catalytic systems based on easily available materials and molecular oxygen for the selective oxidation of alkylarenes is highly desirable. In the present research, NiMn hydrotalcite (Ni2Mn-LDH) has been found as an efficient catalyst in the oxidation of alkylarenes using molecular oxygen as the sole oxidant without any additive. Impressive catalytic performance, excellent stability and recyclability, broad applicable scope and practical potential for the catalytic system have been observed. Mn3+ species was proposed to be the efficient active site, and Ni2+ played an important role in stabilizing the Mn3+ species in the hydrotalcite structure. The kinetic study showed that the aerobic oxidation of diphenylmethane is a first-order reaction over Ni2Mn-LDH with the activation energy (E-a) and pre-exponential factor (A(0)) being 85.7 kJ mol(-1) and 1.8 x 109 min(-1), respectively. The Gibbs free energy (Delta G(not equal)) was determined to be -10.4 kJ mol(-1) K-1 for the oxidation based on Eyring-Polanyi equation, indicating the reaction is exergonic. The mechanism study indicated that the reaction proceeded through both radical and carbocation intermediates. The two species were then trapped by molecular oxygen and H2O or hydroxyl species, respectively, to yield the corresponding products. The present research might provide information for constructing highly efficient and stable active site for the catalytic aerobic oxidation based on available and economic material.

Product Details of 91-02-1. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Wang, AW; Zhou, WY; Sun, ZH; Zhang, Z; Zhang, ZH; He, MY; Chen, Q or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

SDS of cas: 91-02-1. In 2019.0 CHEM COMMUN published article about ELECTROCATALYTIC ALCOHOL OXIDATION; CATALYZED OXIDATION; HYDROCARBON OXIDATION; MOLECULAR-OXYGEN; METAL; FUNCTIONALIZATION; GREEN; CAPROLACTAMATE; CHEMISTRY; TEMPO in [Marko, Jason A.; Durgham, Anthony; Bretz, Stacey Lowery; Liu, Wei] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA in 2019.0, Cited 57.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.

Oxidized products have become increasingly valuable as building blocks for a wide variety of different processes and fine chemistry, especially in the benzylic position. We report herein a sustainable protocol for this transformation through C-H functionalization and is performed using electrochemistry as the main power source and tert-butyl hydroperoxide as the radical source for the C-H abstraction. The temperature conditions reported here do not increase above 50 degrees C and use an aqueous-based medium. A broad substrate scope is explored, along with bioactive molecules, to give comparable and increased product yields when compared to prior reported literature without the use of electrochemistry.

About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Marko, JA; Durgham, A; Bretz, SL; Liu, W or concate me.. SDS of cas: 91-02-1

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Name: Phenyl(pyridin-2-yl)methanone. Recently I am researching about MULTINUCLEAR MAGNETIC-RESONANCE; X-RAY-DIFFRACTION; SOLID-STATE NMR; INTERMOLECULAR INTERACTIONS; OXIDATIVE AMINATION; FACILE SYNTHESIS; BLUE-LIGHT; COMPLEXES; EFFICIENT; IMIDAZO, Saw an article supported by the . Published in ELSEVIER SCI LTD in OXFORD ,Authors: Volpi, G; Garino, C; Priola, E; Magistris, C; Chierotti, MR; Barolo, C. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone

A series of halogenated imidazo[1,5-alpha]pyridines was prepared and their structural and optical properties investigated. The products were characterized by spectroscopic techniques and their optical properties discussed in relation to their chemical structure. We were able to triplicate the luminescence quantum yields (phi) in solution for three different imidazo[1,5-alpha]pyridine derivatives, depending on the halogen nature of the substituent on the imidazo[1,5-alpha]pyridine moiety. The effect of the halogen and of the geometrical and chemical characteristics of the molecular skeleton on the crystal packing was studied in the solid state by single crystal X-ray diffraction. At the same time, the possible presence of halogen bonds was evaluated through solid-state NMR analysis.

Name: Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Volpi, G; Garino, C; Priola, E; Magistris, C; Chierotti, MR; Barolo, C or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Safety of Phenyl(pyridin-2-yl)methanone. Li, DD; Ma, XY; Wang, QZ; Ma, PT; Niu, JY; Wang, JP in [Li, Dandan; Ma, Xinyi; Wang, Quanzhong; Ma, Pengtao; Niu, Jingyang; Wang, Jingping] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Henan, Peoples R China published Copper-Containing Polyoxometalate-Based Metal-Organic Frameworks as Highly Efficient Heterogeneous Catalysts toward Selective Oxidation of Alkylbenzenes in 2019.0, Cited 75.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.

With a one-pot assembly method, two copper-containing Keggin-type polyoxometalate-based metal-organic frameworks (POMOFs), i.e., [Cu-6(I)(trz)(6){PW12O40}(2)] (HENU-2, HENU = Henan University; trz = 1,2,4- triazole) and [Cu-3(I)(trz)(3){PMo12O40}] (HENU-3), were successfully prepared and structurally characterized. These two compounds, which are generated by the extension of a crown-like {Cu-6(trz)(6)} macrocycle-based sandwich-type structural unit, possess identical noninterpenetration 3D frameworks except for the polyanions difference. Additionally, both of them are assessed as highly effective heterogeneous catalysts in facilitating the oxidation of alkylbenzenes to ketone products in the presence of tert-butyl hydroperoxide. Under optimized conditions, HENU-2 can achieve a 95.2% conversion of diphenylmethane in 20 h with a 100% selectivity toward benzophenone, and it was reused for three runs with constant high activity, which outperforms most POM-based catalysts for this catalytic reaction.

Safety of Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Li, DD; Ma, XY; Wang, QZ; Ma, PT; Niu, JY; Wang, JP or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

In 2021 ORG LETT published article about ONE-STEP SYNTHESIS; FUNCTIONALIZATION; 2H-PHOSPHOLES; CHEMISTRY; AMINES in [Liu, Yanjie; Fan, Xinran; Tian, Rongqiang; Duan, Zheng] Zhengzhou Univ, Int Joint Res Lab Funct Organophosphorus Mat Hena, Green Catalysis Ctr, Int Phosphorus Lab,Coll Chem, Zhengzhou 450001, Peoples R China in 2021, Cited 52. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1. Safety of Phenyl(pyridin-2-yl)methanone

We have developed an unprecedented approach for the synthesis of transient 1-phosphafulvenes through three component reactions of phospholes. The generation of 1-phosphafulvenes was demonstrated by in situ [6 + 4] cycloaddition with 2H-phospholes and [6 + 6] self-dimerization. The [6 + 4] and [6 + 6] reaction pathway could be modulated by the starting ketones and aldehydes. The construction of 1-phosphafulvenes is illustrated by a proposed mechanism combining nucleophilic addition of phospholide to the iminium or isomerized azomethine ylide and a [1,5]-shift of phosphole.

Safety of Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Liu, YJ; Fan, XR; Tian, RQ; Duan, Z or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

I found the field of Chemistry very interesting. Saw the article AIBN for Ru-catalyzed meta-C-Ar-H alkylation published in 2020.0. SDS of cas: 91-02-1, Reprint Addresses Li, G (corresponding author), Anyang Normal Univ, Coll Chem & Chem Engn, Henan Prov Key Lab New Optoelect Funct Mat, Anyang 455002, Peoples R China.. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone

Themeta-C-Ar-H alkylation of arenes with radicals produced from AIBN in the presence of a RuCl(3)catalyst is presented. This development not only confirmed that ruthenium-catalyzedmeta-C-Ar-H bond functionalization is a radical process, but also provided an efficient and practical strategy for the preparation of aromatic compounds containing a nitrile group, which are prevalent in a diverse range of biologically active molecules and other functional materials.

SDS of cas: 91-02-1. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Yang, SL; Yan, BX; Zhong, L; Jia, CQ; Yao, D; Yang, CL; Sun, K; Li, G or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

An article Substituent Position-Controlled Stereoselectivity in Enzymatic Reduction of Diaryl- and Aryl(heteroaryl)methanones WOS:000467075800018 published article about ACTIVE ALPHA-PHENYLPYRIDYLMETHANOLS; ARYL HETEROARYL KETONES; ENANTIOSELECTIVE REDUCTION; ASYMMETRIC-SYNTHESIS; KLUYVEROMYCES-MARXIANUS; BIOCATALYTIC SYNTHESIS; CARBONYL REDUCTASE; CELL-CULTURES; SUBSTRATE; BIOREDUCTION in [Li, Zhining; Wang, Zexu; Wang, Yuhan; Huang, Zedu; Chen, Fener] Fudan Univ, Engn Ctr Catalysis & Synth Chiral Mol, Dept Chem, 220 Handan Rd, Shanghai 200433, Peoples R China; [Li, Zhining; Wang, Zexu; Huang, Zedu; Chen, Fener] Shanghai Engn Res Ctr Ind Asymmetr Catalysis Chir, 220 Handan Rd, Shanghai 200433, Peoples R China; [Wu, Xiaofan] Fuzhou Univ, Coll Chem Engn, 2 Xueyuan Rd, Fuzhou 350100, Fujian, Peoples R China; [Lu, Hong] Fudan Univ, Sch Life Sci, State Key Lab Genet Engn, 2005 Songhu Rd, Shanghai 200438, Peoples R China; [Lu, Hong] Shanghai Engn Res Ctr Ind Microorganisms, 2005 Songhu Rd, Shanghai 200438, Peoples R China in 2019.0, Cited 63.0. SDS of cas: 91-02-1. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1

We report here the discovery of a novel ketoreductase (KRED), named KmCR2, with a broad substrate spectrum on bioreduction of sterically bulky diaryl- and aryl(heteroaryl)methanones. The position of the substituent on aromatic rings (meta versus para or ortho) was revealed to control the stereospecificity of KmCR2. The stereoselective preparation of both enantiomers of diaryl- or aryl(heteroaryl)methanols using strategically engineered substrates with a traceless directing group (bromo group) showcased the potential application of this substrate-controlled bioreduction reaction. The combined use of substrate engineering and protein engineering, was demonstrated to be a useful strategy in efficiently improving stereoselectivity or switching stereopreference of enzymatic processes.

SDS of cas: 91-02-1. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Li, ZN; Wang, ZX; Wang, YH; Wu, XF; Lu, H; Huang, ZD; Chen, F or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem