Site-selective D2O-mediated deuteration of diaryl alcohols via quantum dots photocatalysis was written by Nan, Xiao-Lei;Wang, Yao;Li, Xu-Bing;Tung, Chen-Ho;Wu, Li-Zhu. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Product Details of 91-02-1 This article mentions the following:
Owing to the high synthetic value of deuteration in the pharmaceutical industry, the conversion of a range of aromatic ketones to deuterium-labeled products such as RR1CD(OH) [R = Ph, 4-ClC6H4, 4-BrC6H4, 4-CNC6H4, 4-PhC6H4; R1 = Ph, 2-thienyl, 2-naphthyl, etc.] in good to excellent yields was described. Efficient and site-selective deuteration of benzyl alcs. by D2O with visible light irradiation of quantum dots (QDs), together with gram-scale synthesis and photocatalyst recycling experiments indicated the potential of the developed method in practical organic synthesis. In the experiment, the researchers used many compounds, for example, Phenyl(pyridin-2-yl)methanone (cas: 91-02-1Product Details of 91-02-1).
Phenyl(pyridin-2-yl)methanone (cas: 91-02-1) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Pyridine groups exist in countless molecules, and their applications include catalysis, drug design, molecular recognition, and natural product synthesis.Product Details of 91-02-1