《Manganese-Catalyzed Synthesis of Imines from Primary Alcohols and (Hetero)Aromatic Amines》 was written by Raydan, Daniel; Friaes, Sofia; Viduedo, Nuno; Santos, A. Sofia; Gomes, Clara S. B.; Royo, Beatriz; Marques, M. Manuel B.. Computed Properties of C5H5BrN2 And the article was included in Synlett on August 31 ,2022. The article conveys some information:
Herein, the synthesis of a wide variety of imines through oxidative coupling of alcs. and aromatic amines catalyzed by Mn complexes bearing NN triazole ligands was described. A wide variety of imines in excellent yields (up to 99%) was prepared Mn-based catalysts proved to be highly efficient and versatile, allowing for the first time the preparation of several imines containing N-based heterocycles. In addition to this study using 2-Bromopyridin-3-amine, there are many other studies that have used 2-Bromopyridin-3-amine(cas: 39856-58-1Computed Properties of C5H5BrN2) was used in this study.
2-Bromopyridin-3-amine(cas: 39856-58-1) belongs to anime. Hydrogen peroxide (H2O2) and peroxy acids generally add an oxygen atom to the nitrogen of amines. With primary amines, this step is normally followed by further oxidation, leading to nitroso compounds, RNO, or nitro compounds, RNO2. Secondary amines are converted to hydroxylamines, R2NOH, and tertiary amines to amine oxides, R3NO.Computed Properties of C5H5BrN2