A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Computed Properties of C10H9N3, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1202-34-2, Name is Di(pyridin-2-yl)amine, molecular formula is C10H9N3. In an article, author is Roy, Subhasish,once mentioned of 1202-34-2.
Accelerating Effect of DMAP on CuI Catalyzed Buchwald-Hartwig C-N Coupling: Mechanistic Insight to the Reaction Pathway
An efficient methodology has been developed for C-N cross-coupling reaction between aryl halide and amine using a catalytic system comprised of CuI and N,N-dimethyl amino pyridine (DMAP). Coupling reactions were carried out in DMSO at 120 degrees C in presence of 5 mol% CuI, 20 mol% DMAP and 2.5 equivalent of KOH. Addition of DMAP was found to be beneficial in accelerating the rate of reaction significantly. Both aryl iodides and aryl bromides could be successfully coupled with different primary and secondary amines to furnish the desired cross-coupling product in high yield. A copper complex [Cu(DMAP)(4)I]I made by combining CuI and DMAP was found to produce superior result for the Buchwlad-Hartwig cross coupling reaction. The use of 2 mol% of the copper complex is sufficient to produce high yield of the product.
If you’re interested in learning more about 1202-34-2. The above is the message from the blog manager. Computed Properties of C10H9N3.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem