Tag: M.W=150-200

An article Synthesis, structure and palladium coordination of ambiphilic, pyridine- and phosphine-tethered N-boryl imine ligands WOS:000466327900034 published article about LEWIS-ACID; TRANSFER HYDROGENATION; ALLYLIC AMINATION; BOND-ACTIVATION; COMPLEXES; REACTIVITY; PLATINUM; H-2; COCATALYST; CONVERSION in [Lorenzini, Fabio; Lagueux-Tremblay, Pierre-Louis; Kayser, Laure V.; Anderson, Ethan; Arndtsen, Bruce A.] McGill Univ, Dept Chem, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada in 2019.0, Cited 56.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1. Name: Phenyl(pyridin-2-yl)methanone

We describe here the synthesis and structural characterization of two new classes of ambiphilic, N-boryl imine ligands, wherein boron is associated with a Lewis basic imine nitrogen. These ligands can be easily generated in two steps from the corresponding pyridinyl- and phosphinyl-tethered aldehydes. B-11 NMR analysis suggests the association of the Lewis acidic boron to either the pyridine unit or via intermolecular acid/base interactions with the imine. Both of these ligands can coordinate to palladium, and their structures were confirmed by X-ray crystallography.

Welcome to talk about 91-02-1, If you have any questions, you can contact Lorenzini, F; Lagueux-Tremblay, PL; Kayser, LV; Anderson, E; Arndtsen, BA or send Email.. Name: Phenyl(pyridin-2-yl)methanone

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

In 2019.0 J FLUORESC published article about FLUORESCENT-PROBE; ENDOGENOUS HYPOCHLORITE; RATIOMETRIC DETECTION; REAL APPLICATION; NAKED-EYE; TAP WATER; LIVE CELLS; MITOCHONDRIA; MOLECULES; OXIDATION in [Hwang, Suh Mi; Yun, Dongju; Kim, Cheal] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 129743, South Korea in 2019.0, Cited 55.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1. COA of Formula: C12H9NO

A new fluorometric chemodosimeter 2-amino-3-(((E)-3-(1-phenylimidazo[1,5-]pyridin-3-yl)benzylidene)amino)maleonitrile (BPI-MAL) has been designed and synthesized for sensing hypochlorite. BPI-MAL showed a selective turn-on fluorescence for ClO- through hypochlorite-promoted de-diaminomaleonitrile reaction. It also could detect ClO- in the presence of various competitive anions including reactive oxygen species. Interestingly, sensor BPI-MAL was successfully applied as a fluorescent test kit for ClO- determination. The sensing property and mechanism of BPI-MAL toward ClO- were studied by fluorescence and UV-vis spectroscopy, NMR titration and DFT calculations.

COA of Formula: C12H9NO. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Hwang, SM; Yun, D; Kim, C or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

In 2019.0 ANGEW CHEM INT EDIT published article about FUNCTIONALIZED GRAPHENE NANOPLATELETS; CALCIUM CARBIDE; SOLVENT-FREE; MECHANOCHEMISTRY; FORCE in [Ardila-Fierro, Karen J.; Bolm, Carsten; Hernandez, Jose G.] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany in 2019.0, Cited 64.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1. Name: Phenyl(pyridin-2-yl)methanone

A mechanochemical synthesis of one-dimensional carbon allotrope carbyne model compounds, namely tetraaryl[n]cumulenes (n=3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation-type reaction and the implementation of a solvent-free, acid-free reductive elimination with tin(II) chloride by ball milling.

Bye, fridends, I hope you can learn more about C12H9NO, If you have any questions, you can browse other blog as well. See you lster.. Name: Phenyl(pyridin-2-yl)methanone

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Recently I am researching about METAL-COMPLEXES; 2-BENZOYLPYRIDINE; LIGAND; TRANSFORMATION, Saw an article supported by the Special Account of NCSR Demokritos [10813]. Application In Synthesis of Phenyl(pyridin-2-yl)methanone. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Danelli, P; Tsantis, ST; Kitos, A; Psycharis, V; Raptopoulou, CP; Tsipis, A; Perlepes, SP. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone

Two diastereoisomers of bis(2-benzoylpyridine-O,N)dichloridonickel(II) have been isolated from the reactions of nickel(II) chloride hexahydrate and the organic ligand depending on the reaction solvent (ethanol, acetonitrile) used. DFT studies indicate that one of the isomers is more stable in both solvents, but nevertheless different diastereoisomers are crystallized from the two solvents. The two complexes represent the first pair of well characterized diastereoisomers in the coordination chemistry of 2-pyridyl ketones, providing a new example in the chemistry of octahedral MA(2)(BC) over cap (2) complexes (A = a monodentate ligand, (BC) over cap = an unsymmetrical bidentate chelate).

Application In Synthesis of Phenyl(pyridin-2-yl)methanone. Welcome to talk about 91-02-1, If you have any questions, you can contact Danelli, P; Tsantis, ST; Kitos, A; Psycharis, V; Raptopoulou, CP; Tsipis, A; Perlepes, SP or send Email.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Category: pyridine-derivatives. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; N-HETEROCYCLIC CARBENE; PYRAZOLYL-IMIDAZOLYL LIGAND; CATALYTIC-ACTIVITY; BEARING; KETONES; EFFICIENT; CONSTRUCTION; NITRILES; IMPACT, Saw an article supported by the Council of Scientific and Industrial Research (CSIR) New Delhi, IndiaCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]. Published in WILEY in HOBOKEN ,Authors: Singh, PR; Maji, A; Singh, O; Singh, UP; Ghosh, K. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone

Ruthenium complexes(1-3) have been synthesized using pincer-type ligands L-1 = (E)-2-((2-phenyl-2-(pyridin-2-yl)hydrazono)methyl)pyridine, L-2 = (E)-2-(1-phenyl-2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)pyridine, L-3 = (E)-2-(phenyl(2-phenyl-2-(pyridin-2-yl)hydrazono) methyl)pyridine. The molecular structures of all the complexes 1, 2 and 3 were determined by using single crystal X-ray diffraction. These complexes showed excellent catalytic activities such as transfer hydrogenation and alcohol oxidation. Theoretical calculations have been performed to understand the electronic properties of all the complexes using B3LYP as a function and LANL2DZ as a basis set.

Welcome to talk about 91-02-1, If you have any questions, you can contact Singh, PR; Maji, A; Singh, O; Singh, UP; Ghosh, K or send Email.. Category: pyridine-derivatives

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Name: Phenyl(pyridin-2-yl)methanone. In 2019.0 INORG CHIM ACTA published article about DINUCLEAR COPPER(II) COMPLEX; METAL-ORGANIC FRAMEWORK; MAGNETIC-PROPERTIES; DONOR LIGANDS; POLYMERS; PROPERTY; DICYANAMIDE; PHOTOLUMINESCENCE; NICKEL(II); DESIGN in [Sutradhar, Dipu; Ghosh, Barindra Kumar] Univ Burdwan, Dept Chem, Burdwan 713104, W Bengal, India; [Chowdhury, Habibar] Kabi Nazrul Coll, Dept Chem, Birbhum 731219, W Bengal, India; [Banerjee, Somnath] HBNI, Natl Inst Sci Educ & Res, Sch Chem Sci, Khorda 52050, Odisha, India; [Saha, Nimai Chandra] Univ Burdwan, Dept Zool, Vice Chancellors Res Grp, Burdwan 713104, W Bengal, India in 2019.0, Cited 120.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.

Two neutral pentacoordinate mononuclear cadmium(II) complexes of the type [Cd(L)X-2] [L = N-(pyridin-2′-yl)benzylidene)-2-(piperidin-1-yl)ethane-1,2-diamine; X = Cl, (1) and X = Br, (2)], one neutral hexacoordinate dinuclear compound [Cd(L)(mu-NCS)NCS](2) (3) and one neutral hexacoordinate coordination polymer [Cd(L)(mu-N-3)N-3](n) (4) have been prepared and characterized using microanalytical, spectroscopic, thermal and X-ray crystallographic results. Structural analyses show that each cadmium(II) center in the isostructural compounds 1 and 2 adopts a distorted square pyramidal geometry with a CdN3X2 [X = Cl in 1 and X = Br in 2] chromophore through coordination of three N atoms of L and two terminal halides. In 3 and 4, each metal(II) center affords a distorted octahedral geometry with MN5S (in 3) and MN6 (in 4) chromophores. Each metal(II) center in dinuclear compound 3 is attached to three N-atoms of L, one N-atom of terminal thiocyanate, and one N-atom and one S-atom of two mu(1,3)-bridging thiocyanate units, whereas three N-atoms of L and three N-atoms of one terminal and two mu(1,3)-bridging azide units are bound to each metal(II) center in the coordination polymer 4. Each metal (II) center in 4 is connected to two other metal(II) centers through two different mu(1,3)-azide bridges affording a zigzag one-dimensional (1D) chain. In the crystalline state, mononuclear units in both 1 and 2 are stabilized through intermolecular C-H center dot center dot center dot X (X = Cl in 1 and X = Br in 2) hydrogen bonds promoting to 2D sheet structures. The dinuclear units in 3 pack through cooperative intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds giving rise to a 3D network structure. 1D chains in 4 are stabilized through cooperative intermolecular C-H center dot center dot center dot N hydrogen bonds promoting to a 2D sheet structure. These 2D sheets, in turn, self-assemble through weak noncovalent pi center dot center dot center dot pi interactions to afford a 3D network structure. The thermally stable compounds (1-4) exhibit intraligand (1)(pi-pi*) fluorescence in DMF solutions at room temperature with lifetimes in range 0.83-2.94 ns.

Welcome to talk about 91-02-1, If you have any questions, you can contact Sutradhar, D; Chowdhury, H; Banerjee, S; Saha, NC; Ghosh, BK or send Email.. Name: Phenyl(pyridin-2-yl)methanone

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Recently I am researching about PREDICTION; MOLECULES, Saw an article supported by the Provincial Natural Science Foundation of HunanNatural Science Foundation of Hunan Province [2020JJ6012]; Open Project Program of Hunan Provincial Key Laboratory of Environmental Catalysis & Waste Regeneration (Hunan Institute of Engineering) [2018KF11]. HPLC of Formula: C8H9NO2. Published in NATURE RESEARCH in BERLIN ,Authors: Zeng, RL; Deng, JY; Dang, LM; Yu, XL. The CAS is 614-18-6. Through research, I have a further understanding and discovery of Ethyl nicotinate

A three-descriptor quantitative structure-activity/toxicity relationship (QSAR/QSTR) model was developed for the skin permeability of a sufficiently large data set consisting of 274 compounds, by applying support vector machine (SVM) together with genetic algorithm. The optimal SVM model possesses the coefficient of determination R-2 of 0.946 and root mean square (rms) error of 0.253 for the training set of 139 compounds; and a R-2 of 0.872 and rms of 0.302 for the test set of 135 compounds. Compared with other models reported in the literature, our SVM model shows better statistical performance in a model that deals with more samples in the test set. Therefore, applying a SVM algorithm to develop a nonlinear QSAR model for skin permeability was achieved.

Welcome to talk about 614-18-6, If you have any questions, you can contact Zeng, RL; Deng, JY; Dang, LM; Yu, XL or send Email.. HPLC of Formula: C8H9NO2

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Saptal, VB; Saptal, MV; Mane, RS; Sasaki, T; Bhanage, BM in [Saptal, Vitthal B.; Saptal, Madhuri V.; Mane, Rajendra S.; Bhanage, Bhalchandra M.] Inst Chem Technol, Dept Chem, Mumbai 400019, Maharashtra, India; [Sasaki, Takehiko] Univ Tokyo, Grad Sch Frontier Sci, Dept Complex Sci & Engn, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778561, Japan published Amine-Functionalized Graphene Oxide-Stabilized Pd Nanoparticles (Pd@APGO): A Novel and Efficient Catalyst for the Suzuki and Carbonylative Suzuki-Miyaura Coupling Reactions in 2019.0, Cited 47.0. Application In Synthesis of Phenyl(pyridin-2-yl)methanone. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.

Palladium nanoparticles (NPs) are decorated on the surface of an amine-functionalized graphene oxide (Pd@APGO) and characterized by using various analytical techniques. In this methodology, the surface of graphene oxide is modified using the amine functional groups which help stabilization and distribution of Pd NPs very well and increases the surface electron density of NPs by electron donating from amine groups. This developed catalyst shows a high catalytic activity toward the Suzuki coupling and carbonylative Suzuki-Miyaura coupling reactions at mild reaction conditions. The amine on the graphene oxide plays a very crucial role to stabilize and increase the electron density of Pd NPs and prevents the leaching of Pd metals. The Pd@APGO catalyst showed excellent catalytic activity (>90%) with a large range of substrates for both of the reactions and provides five recycle runs without the loss of its activity.

Application In Synthesis of Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Saptal, VB; Saptal, MV; Mane, RS; Sasaki, T; Bhanage, BM or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

I found the field of Pharmacology & Pharmacy very interesting. Saw the article Novel [1,2,3] triazolo[1,5-a]pyridine derivatives are trypanocidal by sterol biosynthesis pathway alteration published in 2019. Application In Synthesis of Ethyl nicotinate, Reprint Addresses Maya, JD (corresponding author), Univ Chile, Fac Med, Inst Ciencias Biomed ICBM, Clin & Mol Pharmacol Program, Independencia 1027, Santiago 1027, Chile.. The CAS is 614-18-6. Through research, I have a further understanding and discovery of Ethyl nicotinate

Aim: To study a new series of [1,2,3] triazolo[1,5-alpha] pyridine derivatives as trypanocidal agents because current antichagasic pharmacologic therapy is only partially effective. Materials & methods: The effect of the series upon Trypanosoma cruzi epimastigotes and murine macrophages viability, cell cycle, cell death and on the metabolites of the sterol biosynthesis pathway was measured; also, docking in 14 alpha-demethylase was analyzed. Results: Compound 16 inhibits 14 alpha-demethylase producing an imbalance in the cholesterol/ergosterol synthesis pathway, as suggested by a metabolic control and theoretical docking analysis. Consequently, it prevented cell proliferation, stopping the cellular cycle at the G2/M phase, inducing cell death. Conclusion: Although the exact cell death mechanism remained elusive, this series can be used for the further rational design of novel antiparasitic molecules.

Application In Synthesis of Ethyl nicotinate. About Ethyl nicotinate, If you have any questions, you can contact Lapier, M; Ballesteros-Garrido, R; Guzman-Rivera, D; Gonzalez-Herrera, F; Aguilera-Venegas, B; Moncada-Basualto, M; Ballesteros, R; Abarca, B; Pesce, B; Kemmerling, U; Olea-Azar, C; Maya, JD or concate me.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem

Authors Tanaka, N; Usuki, T in WILEY-V C H VERLAG GMBH published article about HORIUTI-POLANYI MECHANISM; STABILIZED PALLADIUM NANOPARTICLES; COPD BIOMARKER DESMOSINE; HETEROGENEOUS CATALYSIS; CARBOXYLIC-ACIDS; IONIC LIQUIDS; AMINES; WATER; HYDRODEHALOGENATION; TRANSFORMATION in [Tanaka, Nao; Usuki, Toyonobu] Sophia Univ, Dept Mat & Life Sci, Fac Sci & Technol, Chiyoda Ku, 7-1 Kioicho, Tokyo 1028554, Japan in 2020.0, Cited 79.0. Recommanded Product: Phenyl(pyridin-2-yl)methanone. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1

Hydrogenation of over a dozen aromatic compounds, including both heteroarenes and arenes, over palladium on carbon (Pd/C, 1-100 mol%) with H-2-balloon pressure at room temperature is reported. Analyses using pyridine as a model substrate revealed that acetic acid was the best solvent, as using only 1 mol% Pd/C provided piperidine quantitatively. Substrate scope analysis and density functional theory calculations indicated that reaction rates are highly dependent on frontier molecular orbital characteristics and the steric bulkiness of substituents. Moreover, the established method was used for the concise synthesis of the anti-Alzheimer drug donepezil (Aricept (R)).

Recommanded Product: Phenyl(pyridin-2-yl)methanone. Bye, fridends, I hope you can learn more about C12H9NO, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem