Bis(phosphine)cobalt Dialkyl Complexes for Directed Catalytic Alkene Hydrogenation was written by Friedfeld, Max R.;Margulieux, Grant W.;Schaefer, Brian A.;Chirik, Paul J.. And the article was included in Journal of the American Chemical Society in 2014.Application In Synthesis of 2-Isopropylpyridine This article mentions the following:
Planar, low-spin cobalt(II) dialkyl complexes bearing bidentate phosphine ligands, (P-P)Co(CH2SiMe3)2, are active for the hydrogenation of geminal and 1,2-disubstituted alkenes. Hydrogenation of more hindered internal and endocyclic trisubstituted alkenes was achieved through hydroxyl group. In the experiment, the researchers used many compounds, for example, 2-Isopropylpyridine (cas: 644-98-4Application In Synthesis of 2-Isopropylpyridine).
2-Isopropylpyridine (cas: 644-98-4) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Application In Synthesis of 2-Isopropylpyridine